Generally, VAT Number will automatically populate on your invoice's if you set up it succesfully.
Let's review and checkmark the VAT on the template. Open your invoice from the Custom form style page and go to the Content tab.
Go to the Gear icon ⚙ and select Custom Form Styles.
Click the New Style drop-down button.
Choose Invoice.
Go to the Content tab. Then, click the header part.
Hit Done.
Aside from that, we can also create our own template using an MS Word document. Then, import it into your QBO account. This gives you more flexibility when it comes to the details that you want to be part of your invoices and other sales transactions. Follow the steps in this article for more information: Import Custom Form Styles for Invoices or Estimates.