Let me give you an overview of adding users to QuickBooks Online.
You may have reached the maximum limit of adding users. Depending on what product you currently subscribe with QuickBooks, you can refer to this table:
Note: Only admins and standard users count toward your billable user limit.
It's why you're unable to select the option Company admin and Standard user.
To check your subscription, you can go to the Gear icon and then select Account and Settings. Choose Billing & Subscription.