Thanks for checking in with us. I'll share some information about how you can add a purchase order (PO) number to your invoice in QuickBooks Online (QBO).
The ability to create custom fields on an invoice template is only available on the Plus, Essentials, or Advanced versions of QuickBooks Online. If you're using Simple Start, please note this option is unavailable.
I recommend upgrading your plan from Simple Start to Essentials to take advantage of this feature. I'll show you how.