You'll need to enter the full VAT rate upon creating your transactions to receive a 100% VAT payment.
To do that, click on the + New icon at the left pane and select Invoice. Once done, enter the information needed on the entry and select the full rate of the VAT that you're going to use. Please see the sample screenshot attached for reference:
I've added here some great links that you can visit about entering VAT in QuickBooks Online and on what are the common codes to be used: